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      A Review on Membrane Technology and Chemical Surface Modification for the Oily Wastewater Treatment

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          Abstract

          Cleaning of wastewater for the environment is an emerging issue for the living organism. The separation of oily wastewater, especially emulsified mixtures, is quite challenged due to a large amount of wastewater produced in daily life. In this review, the membrane technology for oily wastewater treatment is presented. In the first part, the global membrane market, the oil spill accidents and their results are discussed. In the second and third parts, the source of oily wastewater and conventional treatment methods are represented. Among all methods, membrane technology is considered the most efficient method in terms of high separation performance and easy to operation process. In the fourth part, we provide an overview of membrane technology, fouling problem, and how to improve the self-cleaning surface using functional groups for effectively treating oily wastewater. The recent development of surface-modified membranes for oily wastewater separation is investigated. It is believed that this review will promote understanding of membrane technology and the development of surface modification strategies for anti-fouling membranes.

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          Most cited references71

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          Membrane technology enhancement in oil–water separation. A review

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            A review of treating oily wastewater

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              Study the self cleaning, antibacterial and photocatalytic properties of TiO2 entrapped PVDF membranes.

              The modified PVDF membranes were prepared by adding different amounts of TiO(2) particles (0-4 wt.%) into the casting solution. The TiO(2) entrapped PVDF membranes (0-4% PVDF/TiO(2)) were tested for its antibacterial property by using Escherichia Coliform (E. Coli), photoactive property using Reactive Black 5 (RB5) dye and self cleaning (antifouling) properties by fouling using 1% BSA solution. Results showed that TiO(2) addition significantly affects the pore size and hydrophilicity of the PVDF/TiO(2) membrane. This also improves the flux and permeability of modified PVDF/TiO(2) membrane. The results of antibacterial study showed that the composite PVDF/TiO(2) membrane removes E. Coli at a very faster rate than neat PVDF membrane and membrane with 4% TiO(2) possess highest antibacterial property. The RB5 dye removal using PVDF/TiO(2) occurs under UV by photolysis and photocatalysis mechanisms. The rate of RB5 dye color removal was faster as compared to the rate of aromatic ring structure. The resistance study showed 2% TiO(2) membrane having lower fouling resistance as compared to others. The fouling resistance caused by loosely bound protein (R(c)) was lower than the strongly bound protein (R(f)). The performance of fouled membranes flux and TMP can be recovered to its initial value by simple UV treatment.
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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                20 January 2020
                January 2020
                : 13
                : 2
                : 493
                Affiliations
                [1 ]Centre for Nanomaterials, Advanced Technology and Innovation, Department of Nanomaterials and Informatics, Technical University of Liberec, Studentska 1402/2, 46117 Liberec, Czech Republic; evrenboyraz@ 123456gmail.com (E.B.); jiri.maryska@ 123456tul.cz (J.M.); klara.kucerova2@ 123456tul.cz (K.K.)
                [2 ]Faculty of Mechatronics, Institute for New Technologies and Applied Informatics, Technical University of Liberec, Studentska 1402/2, 46117 Liberec, Czech Republic
                Author notes
                Author information
                https://orcid.org/0000-0002-5057-3718
                https://orcid.org/0000-0003-1118-6085
                Article
                materials-13-00493
                10.3390/ma13020493
                7013497
                31968692
                d9261daa-3b3f-428f-99a3-3edbe2172dfb
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 27 November 2019
                : 15 January 2020
                Categories
                Review

                oil separation,nanomaterial,membrane,self-cleaning,surface modification

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