Advances in Heterogeneous Catalysts for Lignin Hydrogenolysis

Abstract

Lignin is the main component of lignocellulose and the largest source of aromatic substances on the earth. Biofuel and bio‐chemicals derived from lignin can reduce the use of petroleum products. Current advances in lignin catalysis conversion have facilitated many of progress, but understanding the principles of catalyst design is critical to moving the field forward. In this review, the factors affecting the catalysts (including the type of active metal, metal particle size, acidity, pore size, the nature of the oxide supports, and the synergistic effect of the metals) are systematically reviewed based on the three most commonly used supports (carbon, oxides, and zeolites) in lignin hydrogenolysis. The catalytic performance (selectivity and yield of products) is evaluated, and the emerging catalytic mechanisms are introduced to better understand the catalyst design guidelines. Finally, based on the progress of existing studies, future directions for catalyst design in the field of lignin depolymerization are proposed.

Abstract

In this review, factors affecting catalyst performance are systematically summarized based on the three most commonly used supports (carbon, oxides, and zeolites) in lignin hydrogenolysis. The catalytic performance is evaluated, and the emerging catalytic mechanisms are introduced to better understand the catalyst design guidelines. Finally, future directions for catalyst design and catalytic conversion of lignin are prospected.