Artificial light-harvesting n-type porphyrin for panchromatic organic photovoltaic devices†

Abstract

We developed a novel NIR-harvesting n-type porphyrin derivative, PDI–P _Zn–PDI, that shows a low bandgap of 1.27 eV. Panchromatic absorption was extended to the NIR area with a significantly low energy loss of 0.54 eV which led to promising photovoltaic performance.

Abstract

A near-infrared-harvesting n-type porphyrin-based acceptor for organic photovoltaics (OPVs) was developed. The n-type acceptor, PDI–P _Zn–PDI, was designed by connecting a zinc porphyrin (P _Zn) core to two perylenediimide (PDI) wings through ethyne bridges. A narrow bandgap of 1.27 eV was achieved through the extended π-conjugation and intramolecular charge transfer between the strongly electron-donating P _Zn core and the electron-accepting PDI wings. A bulk heterojunction (BHJ) structured photovoltaic device fabricated from PDI–P _Zn–PDI with PTB7-Th exhibited panchromatic photon-to-current conversion from 350 to 900 nm. A power conversion efficiency of 5.25% with a remarkably low E _loss of 0.54 eV was achieved by optimizing the nanomorphology of the BHJ films by adding pyridine and by controlling the ZnO/BHJ interfacial properties.

Notes

†Electronic supplementary information (ESI) available: ¹H and ¹³C NMR, MALDI-TOF-MS, TGA and PL spectra, SCLC graph and photovoltaic properties are provided in detail. See DOI: 10.1039/c7sc01275f