Ni(I)–Alkyl
Complexes Bearing Phenanthroline
Ligands: Experimental Evidence for CO 2  Insertion at Ni(I)
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Abstract

Although the catalytic carboxylation of unactivated alkyl electrophiles has reached remarkable levels of sophistication, the intermediacy of (phenanthroline)Ni(I)–alkyl species—complexes proposed in numerous Ni-catalyzed reductive cross-coupling reactions—has been subject to speculation. Herein we report the synthesis of such elusive (phenanthroline)Ni(I) species and their reactivity with CO ₂, allowing us to address a long-standing question related to Ni-catalyzed carboxylation reactions.

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Author and article information

Journal

Journal ID (nlm-ta): J Am Chem Soc

Journal ID (iso-abbrev): J Am Chem Soc

Journal ID (publisher-id): ja

Journal ID (coden): jacsat

Title: Journal of the American Chemical Society

Publisher: American Chemical Society

ISSN (Print): 0002-7863

ISSN (Electronic): 1520-5126

Publication date (Electronic): 10 June 2020

Publication date (Print): 24 June 2020

Volume: 142

Issue: 25

Pages: 10936-10941

Affiliations

[† ]Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Av. Països Catalans 16, 43007 Tarragona, Spain

[‡ ]Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili , c/Marcel·lí Domingo 1, 43007 Tarragona, Spain

[§ ]ICREA , Passeig Lluís Companys 23, 08010 Barcelona, Spain

[∥ ]Hylleraas Center for Quantum Molecular Sciences, Department of Chemistry, UiT The Arctic University of Norway , N-9307 Tromsø, Norway

[⊥ ]Department of Chemistry, Yale University , P.O. Box 208107, New Haven, Connecticut 06520, United States

Author notes

[* ] rmartinromo@ 123456iciq.es

[* ] kathrin.hopmann@ 123456uit.no

Article

DOI: 10.1021/jacs.0c04695

PMC ID: 7351122

PubMed ID: 32520556

SO-VID: dd3270e6-2d45-44a7-a9bc-68e1549d9268

License:

Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained ( https://creativecommons.org/licenses/by/4.0/).

History

Date received : 29 April 2020

Custom metadata

document-id-old-9 ja0c04695

document-id-new-14 ja0c04695

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ScienceOpen disciplines: Chemistry

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ScienceOpen disciplines: Chemistry

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