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      The Preparation of Alkyltriinethylaininonium–Kaneinite Complexes and Their Conversion to Microporous Materials

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      Bulletin of the Chemical Society of Japan
      The Chemical Society of Japan

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          Intercalated clay catalysts.

          Recent advances in the intercalation of metal complex cations in smectite clay minerals are leading to the development of new classes of selective heterogeneous catalysts. The selectivity of both metal-catalyzed and proton-catalyzed chemical conversions in clay intercalates can often be regulated by controlling surface chemical equilibria, interlamellar swelling, or reactant pair proximity in the interlayer regions. Also, the intercalation of polynuclear hydroxy metal cations and metal cluster cations in smectites affords new pillared clay catalysts with pore sizes that can be made larger than those of conventional zeolite catalysts.
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            Structural studies of silicates by solid-state high-resolution silicon-29 NMR

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              The crystal structure of α-Na2Si2O5

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                Author and article information

                Journal
                Bulletin of the Chemical Society of Japan
                BCSJ
                The Chemical Society of Japan
                0009-2673
                1348-0634
                April 1990
                April 1990
                : 63
                : 4
                : 988-992
                Article
                10.1246/bcsj.63.988
                dddb79f5-82cd-472e-b9eb-5294d6e0c3fe
                © 1990
                History

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