Formation of diamonds in laser-compressed hydrocarbons at planetary interior conditions

Nanodiamonds have excellent mechanical and optical properties, high surface areas and tunable surface structures. They are also non-toxic, which makes them well suited to biomedical applications. Here we review the synthesis, structure, properties, surface chemistry and phase transformations of individual nanodiamonds and clusters of nanodiamonds. In particular we discuss the rational control of the mechanical, chemical, electronic and optical properties of nanodiamonds through surface doping, interior doping and the introduction of functional groups. These little gems have a wide range of potential applications in tribology, drug delivery, bioimaging and tissue engineering, and also as protein mimics and a filler material for nanocomposites.

An understanding of the structure and composition of the giant planets is rapidly evolving because of (i) high-pressure experiments with the ability to study metallic hydrogen and define the properties of its equation of state and (ii) spectroscopic and in situ measurements made by telescopes and satellites that allow an accurate determination of the chemical composition of the deep atmospheres of the giant planets. However, the total amount of heavy elements that Jupiter, Saturn, Uranus, and Neptune contain remains poorly constrained. The discovery of extrasolar giant planets with masses ranging from that of Saturn to a few times the mass of Jupiter opens up new possibilities for understanding planet composition and formation. Evolutionary models predict that gaseous extrasolar giant planets should have a variety of atmospheric temperatures and chemical compositions, but the radii are estimated to be close to that of Jupiter (between 0.9 and 1.7 Jupiter radii), provided that they contain mostly hydrogen and helium.