Sponge-like nanoporous activated carbon from corn husk as a sustainable and highly stable supercapacitor electrode for energy storage

Gas adsorption is an important tool for the characterisation of porous solids and fine powders. Major advances in recent years have made it necessary to update the 1985 IUPAC manual on Reporting Physisorption Data for Gas/Solid Systems. The aims of the present document are to clarify and standardise the presentation, nomenclature and methodology associated with the application of physisorption for surface area assessment and pore size analysis and to draw attention to remaining problems in the interpretation of physisorption data.

Activated carbon (AC) is an important material in various fields owing to its low cost, well-developed porosity, and favorable chemical stability. Key factors for the optimal synthesis of AC are the carbon precursors, activation pathways, activating agents, and design of the procedure parameters. So far, no case studies have reviewed the activating agents used during the chemical activation process. Accordingly, the present review provides a summary of recent research, highlighting the development of activating agents during the process of AC. Detailed lists of pore-forming mechanisms by various activating agents, including alkaline, acidic, neutral, and self-activating agents, have been systematically summarized. Furthermore, the effects of activating agents on the experimental procedures have also been established. Finally, a comprehensive discussion about the influences of activating agents on the physical and chemical properties of the resultant AC is included. The objective of this study is to reveal and distinguish the individual roles of different activating agents during AC synthesis.