Security requirements for process control systems can be viewed as a social construct derived from the culture and society within which the requirement is said to exist. To capture and understand these requirements we need to make use of a formal reasoning system that supports a rigorous deductive process. Socio–Technical Systems thinking offers us the ability to express the wider socio–context within which an ICT system can be said to operate. In this paper we will extend the π-calculus model of actions via the creation of role logic. Then via the application of responsibility modelling and role logic we will demonstrate how a model of a Socio–Technical process control system can be created and analysed so as to identify critical dependancies.