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      Effect of microstructure change on permeability of flax-fiber reinforced silty clay soaked with zinc-ion solution

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          Abstract

          With the application of fiber-reinforcement technology, the mechanical properties of silty clay are improved with fiber reinforcement. However, the variation of permeability coefficient and other parameters of flax-fiber reinforced silty clay have not been sufficiently studied. In this study, the permeability of flax-fiber reinforced silty clay soaked with zinc-contaminated solution under different osmotic pressure was tested by a flexible-wall permeameter, and the effects of zinc-ion concentration and confining pressure on the permeability of flax-fiber reinforced silty clay were studied. Genius XRF was employed to detect the types and quantity of metal elements in the specimens, thereafter, the reasons for the change of permeability were explained from chemical and microscopic perspective. The results showed that the permeability coefficient of flax-fiber reinforced silty clay decreased significantly with the increase of zinc-ion concentration in a low concentration (about 1–10 mg L −1). While in a high concentration (about 100 mg L −1), the permeability coefficient of flax-fiber reinforced silty clay changed little with the increase of zinc-ion concentration. While the flax-fiber reinforced silty clay was not soaked with zinc-ion solution, the permeability coefficient of the specimen increased with the increase of confining pressure. However, when the flax-fiber reinforced silty clay was soaked with zinc-contaminated solution, the permeability coefficient first decreased and then tended to be constant with the increase of confining pressure. With the increase of confining pressure, the porosity of flax-fiber reinforced silty clay decreased, and with the increase of zinc-ion concentration, the porosity of flax-fiber reinforced silty clay first increased and then decreased.

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          Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red-mud.

          We evaluated the effectiveness of lime and red mud (by-product of aluminium manufacturing) to reduce metal availability to Festuca rubra and to allow re-vegetation on a highly contaminated brown-field site. Application of both lime and red mud (at 3 or 5%) increased soil pH and decreased metal availability. Festuca rubra failed to establish in the control plots, but grew to a near complete vegetative cover on the amended plots. The most effective treatment in decreasing grass metal concentrations in the first year was 5% red mud, but by year two all amendments were equally effective. In an additional pot experiment, P application in combination with red mud or lime decreased the Pb concentration, but not total uptake of Pb in Festuca rubra compared to red mud alone. The results show that both red mud and lime can be used to remediate a heavily contaminated acid soil to allow re-vegetation.
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            Immobilization of Zn, Cu, and Pb in contaminated soils using phosphate rock and phosphoric acid.

            Considerable research has been done on P-induced Pb immobilization in Pb-contaminated soils. However, application of P to soils contaminated with multiple heavy metals is limited. The present study examined effectiveness of phosphoric acid (PA) and/or phosphate rock (PR) in immobilizing Pb, Cu, and Zn in two contaminated soils. The effectiveness was evaluated using water extraction, plant uptake, and a simple bioaccessibility extraction test (SBET) mimicking metal uptake in the acidic environment of human stomach. The possible mechanisms for metal immobilization were elucidated using X-ray diffraction, scanning electron microscopy, and chemical speciation program Visual MINTEQ. Compared to the control, all P amendments significantly reduced Pb water solubility, phytoavailability, and bioaccessibility by 72-100%, 15-86%, and 28-92%, respectively. The Pb immobilization was probably attributed to the formation of insoluble Pb phosphate minerals. Phosphorus significantly reduced Cu and Zn water solubility by 31-80% and 40-69%, respectively, presumably due to their sorption on minerals (e.g., calcite and phosphate phases) following CaO addition. However, P had little effect on the Cu and Zn phytoavailability; while the acid extractability of Cu and Zn induced by SBET (pH 2) were even elevated by up to 48% and 40%, respectively, in the H(3)PO(4) treatments (PA and PR+PA). Our results indicate that phosphate was effective in reducing Pb availability in terms of water solubility, bioaccessibility, and phytoavailability. Caution should be exercised when H(3)PO(4) was amended to the soil co-contaminated with Cu and Zn since the acidic condition of SBET increased Cu and Zn bioaccessibility though their water solubility was reduced.
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              Engineering properties and microstructural characteristics of cement-stabilized zinc-contaminated kaolin

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                Author and article information

                Contributors
                xiao-henglin@163.com
                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group UK (London )
                2045-2322
                9 July 2020
                9 July 2020
                2020
                : 10
                : 11296
                Affiliations
                ISNI 0000 0000 8822 034X, GRID grid.411410.1, School of Civil Engineering and Environment, , Hubei University of Technology, ; Wuhan, People’s Republic of China
                Article
                68332
                10.1038/s41598-020-68332-4
                7347911
                32647348
                557d1949-93ab-4155-bc98-91ed3c9f0c85
                © The Author(s) 2020

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 14 January 2020
                : 23 June 2020
                Funding
                Funded by: National Key Rand D Program of China
                Award ID: 2016YFC0502208
                Funded by: National Natural Science Foundation of China (NSFC)
                Award ID: 51678223
                Award ID: 51608182
                Funded by: the Major Projects of Technical Innovation in Hubei
                Award ID: 2017AAA128
                Categories
                Article
                Custom metadata
                © The Author(s) 2020

                Uncategorized
                environmental chemistry,environmental impact
                Uncategorized
                environmental chemistry, environmental impact

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