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      Sonochemically assisted the synthesis and catalytic application of bismuth-based photocatalyst: A mini review

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          Highlights

          • This review focuses on the paths for Bi-based materials to profit from sonochemistry.

          • The roles of ultrasound in the process of material formation are introduced.

          • Inherent functionality of sonochemistry in photocatalysis is clarified.

          • Photocatalytic applications and status of enhanced Bi-based materials are discussed.

          • Future directions for ultrasonic synergistic Bi-based photocatalysts are presented.

          Abstract

          Recently, bismuth (Bi)-based photocatalysts have been a well-deserved hotspot in the field of photocatalysis owning to their photoelectrochemical properties driven by the distortion of the Bi 6 s orbital, while their narrow band gap and poor quantum efficiency still restrict their application. With the development of ultrasonic technology, it is expected to become a broom to clear the application obstacles of Bi-based photocatalysts. The special forces and environmental conditions brought by ultrasonic irradiation play beneficial roles in the preparation, modification and performance releasement of Bi-based photocatalysts. In this review, the role and influencing factors of ultrasound in the preparation and modification of Bi-based photocatalysts were introduced. Crucially, the mechanism of the improving the performance for various types of Bi-based photocatalysts by ultrasound in the whole process of photocatalysis was deeply analyzed. Then, the application of ultrasonic synergistic Bi-based photocatalysts in contaminants treatment and energy conversion was briefly introduced. Finally, based on an unambiguous understanding of ultrasonic technology in assisting Bi-based photocatalysts, the future directions and possibilities for ultrasonic synergistic Bi-based photocatalysts are explored.

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          Most cited references160

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          Electrochemical Photolysis of Water at a Semiconductor Electrode

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            Heterojunction Photocatalysts.

            Semiconductor-based photocatalysis attracts wide attention because of its ability to directly utilize solar energy for production of solar fuels, such as hydrogen and hydrocarbon fuels and for degradation of various pollutants. However, the efficiency of photocatalytic reactions remains low due to the fast electron-hole recombination and low light utilization. Therefore, enormous efforts have been undertaken to solve these problems. Particularly, properly engineered heterojunction photocatalysts are shown to be able to possess higher photocatalytic activity because of spatial separation of photogenerated electron-hole pairs. Here, the basic principles of various heterojunction photocatalysts are systematically discussed. Recent efforts toward the development of heterojunction photocatalysts for various photocatalytic applications are also presented and appraised. Finally, a brief summary and perspectives on the challenges and future directions in the area of heterojunction photocatalysts are also provided.
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              Microfibre-nanowire hybrid structure for energy scavenging.

              A self-powering nanosystem that harvests its operating energy from the environment is an attractive proposition for sensing, personal electronics and defence technologies. This is in principle feasible for nanodevices owing to their extremely low power consumption. Solar, thermal and mechanical (wind, friction, body movement) energies are common and may be scavenged from the environment, but the type of energy source to be chosen has to be decided on the basis of specific applications. Military sensing/surveillance node placement, for example, may involve difficult-to-reach locations, may need to be hidden, and may be in environments that are dusty, rainy, dark and/or in deep forest. In a moving vehicle or aeroplane, harvesting energy from a rotating tyre or wind blowing on the body is a possible choice to power wireless devices implanted in the surface of the vehicle. Nanowire nanogenerators built on hard substrates were demonstrated for harvesting local mechanical energy produced by high-frequency ultrasonic waves. To harvest the energy from vibration or disturbance originating from footsteps, heartbeats, ambient noise and air flow, it is important to explore innovative technologies that work at low frequencies (such as <10 Hz) and that are based on flexible soft materials. Here we present a simple, low-cost approach that converts low-frequency vibration/friction energy into electricity using piezoelectric zinc oxide nanowires grown radially around textile fibres. By entangling two fibres and brushing the nanowires rooted on them with respect to each other, mechanical energy is converted into electricity owing to a coupled piezoelectric-semiconductor process. This work establishes a methodology for scavenging light-wind energy and body-movement energy using fabrics.
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                Author and article information

                Contributors
                Journal
                Ultrason Sonochem
                Ultrason Sonochem
                Ultrasonics Sonochemistry
                Elsevier
                1350-4177
                1873-2828
                18 September 2023
                November 2023
                18 September 2023
                : 100
                : 106600
                Affiliations
                [a ]College of Environment and Ecology, Hunan Agricultural University, Changsha 410128, PR China
                [b ]School of Resources and Environment, Hunan University of Technology and Business, Changsha 410205, PR China
                [c ]Key Laboratory for Rural Ecosystem Health in the Dongting Lake Area of Hunan Province, Changsha 410128, PR China
                Author notes
                [* ]Corresponding authors at: College of Environment and Ecology, Hunan Agricultural University, Changsha 410128, PR China (Y. Liang, Z. Wu); School of Resources and Environment, Hunan University of Technology and Business, Changsha, 410205, PR China (J.Y. Guo). lyss3399@ 123456126.com jiayinguoo@ 123456163.com wzbaaa11@ 123456hunau.edu.cn
                Article
                S1350-4177(23)00312-7 106600
                10.1016/j.ultsonch.2023.106600
                10520575
                37741022
                5ab9cf98-de09-408e-b873-5fb0baeedaea
                © 2023 The Authors. Published by Elsevier B.V.

                This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 30 July 2023
                : 11 September 2023
                : 13 September 2023
                Categories
                Original Research Article

                ultrasonic,bi-based photocatalyst,cavitation effect,piezoelectric photocatalysis

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