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      3D porous biomass-derived carbon materials: biomass sources, controllable transformation and microwave absorption application

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          Abstract

          This article reviews 3D porous biomass-derived carbon materials as microwave absorbers, including their biomass sources, the transformation from biomass to porous carbon, and their corresponding microwave absorption applications and mechanism.

          Abstract

          Nowadays, to prevent acute electromagnetic pollution and develop efficient stealth materials, enormous efforts have been taken in pursuit of high-performance microwave absorption (MA) materials. Compared to classical microwave absorbers, biomass-derived porous materials, including natural materials and recyclable materials, have attracted great attention for their extensive sources, cheap cost, low density and reusability. To date, many works have indicated that biomass-based absorbers from different raw materials exhibit excellent MA performance. Herein, various sources of biomass materials that can be utilized for MA are discussed and several common reduction approaches for those materials are analyzed. Additionally, it is significant to understand how to obtain an optimum MA capacity by adjusting relative factors, so reduction conditions are also expounded on. Besides, different morphologies of biomass materials and the relationship between structure and properties are discussed. Finally, we comprehensively summarize biomass-based MA composites with different types of attenuation modes and mechanisms to explain the principal problems and push the development of biomass-based porous MA materials forward.

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          Electromagnetic interference shielding with 2D transition metal carbides (MXenes)

          Materials with good flexibility and high conductivity that can provide electromagnetic interference (EMI) shielding with minimal thickness are highly desirable, especially if they can be easily processed into films. Two-dimensional metal carbides and nitrides, known as MXenes, combine metallic conductivity and hydrophilic surfaces. Here, we demonstrate the potential of several MXenes and their polymer composites for EMI shielding. A 45-micrometer-thick Ti3C2Tx film exhibited EMI shielding effectiveness of 92 decibels (>50 decibels for a 2.5-micrometer film), which is the highest among synthetic materials of comparable thickness produced to date. This performance originates from the excellent electrical conductivity of Ti3C2Tx films (4600 Siemens per centimeter) and multiple internal reflections from Ti3C2Tx flakes in free-standing films. The mechanical flexibility and easy coating capability offered by MXenes and their composites enable them to shield surfaces of any shape while providing high EMI shielding efficiency.
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            Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam.

            The broadband and tunable high-performance microwave absorption properties of an ultralight and highly compressible graphene foam (GF) are investigated. Simply via physical compression, the microwave absorption performance can be tuned. The qualified bandwidth coverage of 93.8% (60.5 GHz/64.5 GHz) is achieved for the GF under 90% compressive strain (1.0 mm thickness). This mainly because of the 3D conductive network.
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              Reduced graphene oxides: light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures.

              Chemical graphitized r-GOs, as the thinnest and lightest material in the carbon family, exhibit high-efficiency electromagnetic interference (EMI) shielding at elevated temperature, attributed to the cooperation of dipole polarization and hopping conductivity. The r-GO composites show different temperature-dependent imaginary permittivities and EMI shielding performances with changing mass ratio.
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                Author and article information

                Contributors
                Journal
                GRCHFJ
                Green Chemistry
                Green Chem.
                Royal Society of Chemistry (RSC)
                1463-9262
                1463-9270
                January 24 2022
                2022
                : 24
                : 2
                : 647-674
                Affiliations
                [1 ]School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China
                Article
                10.1039/D1GC02566J
                6c176a0e-982e-4150-949f-00bb16475128
                © 2022

                http://rsc.li/journals-terms-of-use

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