Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages

Shao, Kui-Zhan; Su, Zhong-Min; Zhang, Yu-Teng; Wang, Xin-Long; Zhou, En-Long; Wu, Xue-Song; Song, Bai-Qiao

doi:10.1039/C5DT04764A

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Polyoxovanadate-based organic–inorganic hybrids: from {V5O9Cl} clusters to nanosized octahedral cages

Author(s): Yu-Teng Zhang ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Xin-Long Wang ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , En-Long Zhou ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Xue-Song Wu ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Bai-Qiao Song ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Kui-Zhan Shao ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵ , Zhong-Min Su ¹ ^, ² ^, ³ ^, ⁴ ^, ⁵

Publication date (Electronic): 2016

Journal: Dalton Transactions

Publisher: Royal Society of Chemistry (RSC)

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Abstract

Three nanosized polyoxovanadate-based metal–organic polyhedra have been successfully synthesized, which adopt isostructural octahedral cage geometries.

Abstract

Three polyoxovanadate-based metal–organic polyhedra (denoted as VMOP-1, -2, and -3), adopting isostructural discrete octahedral cage geometries, were successfully synthesized under solvothermal conditions. These structures are all built up from the same pentavanadate {V ₅O ₉Cl} cluster connected by linear bidentate ligands (H ₂L1 = H ₂BDC, H ₂L2 = H ₂BDC-NH ₂, H ₂L3 = H ₂BDC-Br), respectively.