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      Nanostructures for Light Trapping in Thin Film Solar Cells

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          Abstract

          Thin film solar cells are one of the important candidates utilized to reduce the cost of photovoltaic production by minimizing the usage of active materials. However, low light absorption due to low absorption coefficient and/or insufficient active layer thickness can limit the performance of thin film solar cells. Increasing the absorption of light that can be converted into electrical current in thin film solar cells is crucial for enhancing the overall efficiency and in reducing the cost. Therefore, light trapping strategies play a significant role in achieving this goal. The main objectives of light trapping techniques are to decrease incident light reflection, increase the light absorption, and modify the optical response of the device for use in different applications. Nanostructures utilize key sets of approaches to achieve these objectives, including gradual refractive index matching, and coupling incident light into guided modes and localized plasmon resonances, as well as surface plasmon polariton modes. In this review, we discuss some of the recent developments in the design and implementation of nanostructures for light trapping in solar cells. These include the development of solar cells containing photonic and plasmonic nanostructures. The distinct benefits and challenges of these schemes are also explained and discussed.

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          Most cited references145

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          Research opportunities to advance solar energy utilization.

          Major developments, as well as remaining challenges and the associated research opportunities, are evaluated for three technologically distinct approaches to solar energy utilization: solar electricity, solar thermal, and solar fuels technologies. Much progress has been made, but research opportunities are still present for all approaches. Both evolutionary and revolutionary technology development, involving foundational research, applied research, learning by doing, demonstration projects, and deployment at scale will be needed to continue this technology-innovation ecosystem. Most of the approaches still offer the potential to provide much higher efficiencies, much lower costs, improved scalability, and new functionality, relative to the embodiments of solar energy-conversion systems that have been developed to date.
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            Light trapping in silicon nanowire solar cells.

            Thin-film structures can reduce the cost of solar power by using inexpensive substrates and a lower quantity and quality of semiconductor material. However, the resulting short optical path length and minority carrier diffusion length necessitates either a high absorption coefficient or excellent light trapping. Semiconducting nanowire arrays have already been shown to have low reflective losses compared to planar semiconductors, but their light-trapping properties have not been measured. Using optical transmission and photocurrent measurements on thin silicon films, we demonstrate that ordered arrays of silicon nanowires increase the path length of incident solar radiation by up to a factor of 73. This extraordinary light-trapping path length enhancement factor is above the randomized scattering (Lambertian) limit (2n(2) approximately 25 without a back reflector) and is superior to other light-trapping methods. By changing the silicon film thickness and nanowire length, we show that there is a competition between improved absorption and increased surface recombination; for nanowire arrays fabricated from 8 mum thick silicon films, the enhanced absorption can dominate over surface recombination, even without any surface passivation. These nanowire devices give efficiencies above 5%, with short-circuit photocurrents higher than planar control samples.
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              Surface plasmon enhanced silicon solar cells

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                Author and article information

                Journal
                Micromachines (Basel)
                Micromachines (Basel)
                micromachines
                Micromachines
                MDPI
                2072-666X
                17 September 2019
                September 2019
                : 10
                : 9
                : 619
                Affiliations
                [1 ]Centre for Advanced Photovoltaics, Faculty of Electrical Engineering, Czech Technical University in Prague, Technická 2, 16627 Prague, Czech Republic
                [2 ]Department of Electrical and Computer Engineering, University of Canterbury, Christchurch 8140, New Zealand; maan.alkaisi@ 123456canterbury.ac.nz
                [3 ]MacDiarmid Institute of Advanced Materials and Nanotechnology, Wellington 6140, New Zealand
                Author notes
                [* ]Correspondence: peterama@ 123456fel.cvut.cz
                Author information
                https://orcid.org/0000-0002-9252-1975
                Article
                micromachines-10-00619
                10.3390/mi10090619
                6780776
                31533261
                94f28e01-4557-4c82-9b3c-e55bb1727e57
                © 2019 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 02 September 2019
                : 16 September 2019
                Categories
                Review

                light trapping,solar cells,thin films,photonic nanostructures,plasmonic nanostructures

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