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      Green Synthesized Phytochemically ( Zingiber officinale and Allium sativum) Reduced Nickel Oxide Nanoparticles Confirmed Bactericidal and Catalytic Potential

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          Abstract

          Phyto-synthesized nanoparticles (NPs) having reduced chemical toxicity have been focused globally and become essential component of nanotechnology recently. We prepared green phytochemically (ginger and garlic) reduced NiO-NPs to replace synthetic bactericidal and catalytic agent in textile industry. NPs were characterized using ultra-violet visible spectroscopy (UV-Vis), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The synthesis of NPs was confirmed by XRD and UV-Vis having strong absorption at 350 nm with size ranged between 16–52 nm for ginger and 11–59 nm for garlic. Scanning and transmission electron microscopy confirmed pleomorphism with cubic- and more spherical-shaped NPs. Moreover, exact quantities of garlic and ginger extracts (1:3.6 ml) incorporated to synthesize NiO-NPs have been successfully confirmed by FTIR. Phytochemically reduced NPs by garlic presented enhanced bactericidal activity against multiple drug-resistant Staphylococcus aureus at increasing concentrations (0.5, 1.0 mg/50 μl) and also degraded methylene blue (MB) dye efficiently. Conclusively, green synthesized NiO-NPs are impending activists to resolve drug resistance as well as environment friendly catalytic agent that may be opted at industrial scale.

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          X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems

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            Facile route to an efficient NiO supercapacitor with a three-dimensional nanonetwork morphology.

            NiO nanostructures with three distinct morphologies were fabricated by a sol-gel method and their morphology-dependent supercapacitor properties were exploited. The nanoflower- shaped NiO with a distinctive three-dimensional (3D) network and the highest pore volume shows the best supercapacitor properties. The nanopores in flower-shaped nanostructures, offering advantages in contact with and transport of the electrolyte, allow for 3D nanochannels in NiO structure, providing longer electron pathways. The XPS and EIS data of the NiO nanostructure confirm that the flower-shaped NiO, which has the lowest surface area among the three morphologies, was effectively optimized as a superior electrode and yielded the greatest pseudocapacitance. This study indicates that forming a 3D nanonetwork is a straightforward means of improving the electrochemical properties of a supercapacitor.
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              Valence and Conduction Band Densities of States of Metal Halide Perovskites: A Combined Experimental–Theoretical Study

              We report valence and conduction band densities of states measured via ultraviolet and inverse photoemission spectroscopies on three metal halide perovskites, specifically methylammonium lead iodide and bromide and cesium lead bromide (MAPbI3, MAPbBr3, CsPbBr3), grown at two different institutions on different substrates. These are compared with theoretical densities of states (DOS) calculated via density functional theory. The qualitative agreement achieved between experiment and theory leads to the identification of valence and conduction band spectral features, and allows a precise determination of the position of the band edges, ionization energy and electron affinity of the materials. The comparison reveals an unusually low DOS at the valence band maximum (VBM) of these compounds, which confirms and generalizes previous predictions of strong band dispersion and low DOS at the MAPbI3 VBM. This low DOS calls for special attention when using electron spectroscopy to determine the frontier electronic states of lead halide perovskites.
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                Author and article information

                Contributors
                mijaz@uvas.edu.pk
                dr.muhammadikram@gcu.edu.pk
                Journal
                Nanoscale Res Lett
                Nanoscale Res Lett
                Nanoscale Research Letters
                Springer US (New York )
                1931-7573
                1556-276X
                2 March 2020
                2 March 2020
                2020
                : 15
                : 50
                Affiliations
                [1 ]GRID grid.412967.f, Department of Clinical Medicine and Surgery, , University of Veterinary and Animal Sciences, ; Lahore, Punjab 54000 Pakistan
                [2 ]ISNI 0000 0004 0459 9276, GRID grid.414696.8, Department of Gynaecology& Obstetric (Unit –III), , Jinnah Hospital, ; Lahore, Punjab 54000 Pakistan
                [3 ]ISNI 0000000119573309, GRID grid.9227.e, Tianjin Institute of Industrial Biotechnology, , Chinese Academy of Sciences, ; 32 West 7th Avenue, Tianjin, 300308 China
                [4 ]ISNI 0000 0000 9931 8406, GRID grid.48166.3d, State key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Centre for Soft Matter Science and Engineering, Beijing Engineering Center for Hierarchical Catalysts, , Beijing University of Chemical Technology, ; Beijing, 100029 China
                [5 ]GRID grid.412967.f, Department of Food Sciences, , Cholistan University of Veterinary and Animal Sciences, ; Near DHA663100, Bahawalpur, Pakistan
                [6 ]ISNI 0000 0001 0670 519X, GRID grid.11173.35, University College of Pharmacy, University of the Punjab, ; Lahore, 54000 Pakistan
                [7 ]GRID grid.412967.f, Institute of Biochemistry and Biotechnology, , University of Veterinary and animal sciences, ; Lahore, Punjab 54000 Pakistan
                [8 ]ISNI 0000 0001 2233 7083, GRID grid.411555.1, Solar Cell Applications Research Lab, Department of Physics, , Government College University, ; Lahore, Punjab 54000 Pakistan
                Author information
                http://orcid.org/0000-0001-7741-789X
                Article
                3283
                10.1186/s11671-020-3283-5
                7052104
                32124107
                9e3705bd-c7eb-46a7-ae54-896193a7631a
                © The Author(s). 2020

                Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 11 November 2019
                : 18 February 2020
                Funding
                Funded by: FundRef http://dx.doi.org/10.13039/501100010221, Higher Education Commision, Pakistan;
                Award ID: 21-1669
                Categories
                Nano Express
                Custom metadata
                © The Author(s) 2020

                Nanomaterials
                metal oxide,particle size,diseases
                Nanomaterials
                metal oxide, particle size, diseases

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