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      Cycloadditions to Epoxides Catalyzed by Group III-V Transition-Metal Complexes

      , ,
      ChemCatChem
      Wiley

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          Cu-catalyzed azide-alkyne cycloaddition.

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            Applications of metal-organic frameworks in heterogeneous supramolecular catalysis.

            This review summarizes the use of metal-organic frameworks (MOFs) as a versatile supramolecular platform to develop heterogeneous catalysts for a variety of organic reactions, especially for liquid-phase reactions. Following a background introduction about catalytic relevance to various metal-organic materials, crystal engineering of MOFs, characterization and evaluation methods of MOF catalysis, we categorize catalytic MOFs based on the types of active sites, including coordinatively unsaturated metal sites (CUMs), metalloligands, functional organic sites (FOS), as well as metal nanoparticles (MNPs) embedded in the cavities. Throughout the review, we emphasize the incidental or deliberate formation of active sites, the stability, heterogeneity and shape/size selectivity for MOF catalysis. Finally, we briefly introduce their relevance into photo- and biomimetic catalysis, and compare MOFs with other typical porous solids such as zeolites and mesoporous silica with regard to their different attributes, and provide our view on future trends and developments in MOF-based catalysis.
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              The teraton challenge. A review of fixation and transformation of carbon dioxide

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                Author and article information

                Journal
                ChemCatChem
                ChemCatChem
                Wiley
                18673880
                July 03 2015
                July 03 2015
                : 7
                : 13
                : 1906-1917
                Article
                10.1002/cctc.201500231
                ab7435ee-1572-4e59-8f00-44034ac46b6b
                © 2015

                http://doi.wiley.com/10.1002/tdm_license_1.1

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