Selective UV Reflecting Mirrors Based on Nanoparticle Multilayers

Short-wave ultraviolet light (UVC, 254 nm) can reduce dramatically the microbial load in air or on hard surfaces free from food residues, and can eliminate pathogens from potable water filtered to remove organic residues and 'clumps' of bacteria. More recently, approval of the Food and Drug Administration (USA) has been sought for a system for the destruction of pathogenic bacteria in fruit juices using UVC, and the same approach could perhaps be applied to remove spoilage organisms from cider or wines. In contrast, long-wave UV light (UVA, >320 nm) has limited microbiocidal properties, and for practical applications its effectiveness has to be enhanced by the presence of photosensitive compounds (eg furocoumarins) that will diffuse into a microbial cell prior to irradiation. The penetration of UVA into water is better than that of UVC, and its bacteriocidal action in the presence of photosensitisers can be rapid. However, pure furocoumarins are expensive and their addition to foodstuffs might be questioned on safety grounds. © 2000 Society of Chemical Industry.

One of the most important drawbacks of classical and new advanced functional materials for applications outdoors, or in environments with high UV irradiation, is the light induced damage that reduces drastically their effective operation lifetime or durability. This makes protecting light sensitive materials against UV irradiation a nowadays important technological demand in almost every industrial field. This tutorial review incorporates the main aspects of UV damage to materials and describes the recently developed highly effective thin UV-protective coatings, based on UV-absorber molecules entrapped in a Sol-Gel derived ormosil matrix.