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      In situ observation of the sodiation process in CuO nanowires

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          Abstract

          We observed the dynamic evolution of the morphology and phase transformations of CuO nanowires during sodiation using in situ transmission electron microscopy. These results will facilitate our fundamental understanding of the sodiation mechanism of CuO nanostructures used as electrode materials in sodium ion batteries.

          Abstract

          In situ transmission electron microscopy was used to observe the dynamic evolution of the morphology and phase transformations in CuO nanowires during the process of sodiation. Our results facilitate a fundamental understanding of the sodiation mechanism in CuO nanostructures used as electrode materials in sodium ion batteries.

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          Sodium-Ion Batteries

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            Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries

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              In situ observation of the electrochemical lithiation of a single SnO₂ nanowire electrode.

              We report the creation of a nanoscale electrochemical device inside a transmission electron microscope--consisting of a single tin dioxide (SnO(2)) nanowire anode, an ionic liquid electrolyte, and a bulk lithium cobalt dioxide (LiCoO(2)) cathode--and the in situ observation of the lithiation of the SnO(2) nanowire during electrochemical charging. Upon charging, a reaction front propagated progressively along the nanowire, causing the nanowire to swell, elongate, and spiral. The reaction front is a "Medusa zone" containing a high density of mobile dislocations, which are continuously nucleated and absorbed at the moving front. This dislocation cloud indicates large in-plane misfit stresses and is a structural precursor to electrochemically driven solid-state amorphization. Because lithiation-induced volume expansion, plasticity, and pulverization of electrode materials are the major mechanical effects that plague the performance and lifetime of high-capacity anodes in lithium-ion batteries, our observations provide important mechanistic insight for the design of advanced batteries.
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                Author and article information

                Journal
                CHCOFS
                Chemical Communications
                Chem. Commun.
                Royal Society of Chemistry (RSC)
                1359-7345
                1364-548X
                2015
                2015
                : 51
                : 52
                : 10443-10446
                Affiliations
                [1 ]School of Physics and Technology
                [2 ]Center for Electron Microscopy and MOE Key Laboratory of Artificial Micro- and Nano-structures
                [3 ]Wuhan University
                [4 ]Wuhan 430072
                [5 ]China
                Article
                10.1039/C5CC03734D
                b81dee9a-0c31-41e1-b5b9-4f6ee135b1a9
                © 2015
                History

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