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      The emergence of hydrogeophysics for improved understanding of subsurface processes over multiple scales

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          Abstract

          Geophysics provides a multidimensional suite of investigative methods that are transforming our ability to see into the very fabric of the subsurface environment, and monitor the dynamics of its fluids and the biogeochemical reactions that occur within it. Here we document how geophysical methods have emerged as valuable tools for investigating shallow subsurface processes over the past two decades and offer a vision for future developments relevant to hydrology and also ecosystem science. The field of “hydrogeophysics” arose in the late 1990s, prompted, in part, by the wealth of studies on stochastic subsurface hydrology that argued for better field‐based investigative techniques. These new hydrogeophysical approaches benefited from the emergence of practical and robust data inversion techniques, in many cases with a view to quantify shallow subsurface heterogeneity and the associated dynamics of subsurface fluids. Furthermore, the need for quantitative characterization stimulated a wealth of new investigations into petrophysical relationships that link hydrologically relevant properties to measurable geophysical parameters. Development of time‐lapse approaches provided a new suite of tools for hydrological investigation, enhanced further with the realization that some geophysical properties may be sensitive to biogeochemical transformations in the subsurface environment, thus opening up the new field of “biogeophysics.” Early hydrogeophysical studies often concentrated on relatively small “plot‐scale” experiments. More recently, however, the translation to larger‐scale characterization has been the focus of a number of studies. Geophysical technologies continue to develop, driven, in part, by the increasing need to understand and quantify key processes controlling sustainable water resources and ecosystem services.

          Key Points:

          • A review of the emergence and development of hydrogeophysics

          • Outline of emerging techniques in hydrogeophysics

          • Presentation of future opportunities in hydrogeophysics

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          Most cited references7

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          Effective conductivity and permittivity of unsaturated porous materials in the frequency range 1 mHz–1GHz

          A Revil (2013)
          A model combining low-frequency complex conductivity and high-frequency permittivity is developed in the frequency range from 1 mHz to 1 GHz. The low-frequency conductivity depends on pore water and surface conductivities. Surface conductivity is controlled by the electrical diffuse layer, the outer component of the electrical double layer coating the surface of the minerals. The frequency dependence of the effective quadrature conductivity shows three domains. Below a critical frequency fp , which depends on the dynamic pore throat size Λ, the quadrature conductivity is frequency dependent. Between fp and a second critical frequency fd , the quadrature conductivity is generally well described by a plateau when clay minerals are present in the material. Clay-free porous materials with a narrow grain size distribution are described by a Cole-Cole model. The characteristic frequency fd controls the transition between double layer polarization and the effect of the high-frequency permittivity of the material. The Maxwell-Wagner polarization is found to be relatively negligible. For a broad range of frequencies below 1 MHz, the effective permittivity exhibits a strong dependence with the cation exchange capacity and the specific surface area. At high frequency, above the critical frequency fd , the effective permittivity reaches a high-frequency asymptotic limit that is controlled by the two Archie's exponents m and n like the low-frequency electrical conductivity. The unified model is compared with various data sets from the literature and is able to explain fairly well a broad number of observations with a very small number of textural and electrochemical parameters. It could be therefore used to interpret induced polarization, induction-based electromagnetic methods, and ground penetrating radar data to characterize the vadose zone.
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            Geophysical monitoring of coupled microbial and geochemical processes during stimulated subsurface bioremediation.

            Understanding how microorganisms alter their physical and chemical environment during bioremediation is hindered by our inability to resolve subsurface microbial activity with high spatial resolution. Here we demonstrate the use of a minimally invasive geophysical technique to monitor stimulated microbial activity during acetate amendment in an aquifer near Rifle, Colorado. During electrical induced polarization (IP) measurements, spatiotemporal variations in the phase response between imposed electric current and the resultant electric field correlated with changes in groundwater geochemistry accompanying stimulated iron and sulfate reduction and sulfide mineral precipitation. The magnitude of the phase response varied with measurement frequency (0.125 and 1 Hz) and was dependent upon the dominant metabolic process. The spectral effect was corroborated using a biostimulated column experiment containing Rifle sediments and groundwater. Fluids and sediments recovered from regions exhibiting an anomalous phase response were enriched in Fe(II), dissolved sulfide, and cell-associated FeS nanoparticles. The accumulation of mineral precipitates and electroactive ions altered the ability of pore fluids to conduct electrical charge, accounting for the anomalous IP response and revealing the usefulness of multifrequency IP measurementsfor monitoring mineralogical and geochemical changes accompanying stimulated subsurface bioremediation.
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              Geophysical imaging of stimulated microbial biomineralization.

              Understanding how microorganisms influence the physical and chemical properties of the subsurface is hindered by our inability to observe microbial dynamics in real time and with high spatial resolution. Here, we investigate the use of noninvasive geophysical methods to monitor biomineralization at the laboratory scale during stimulated sulfate reduction under dynamic flow conditions. Alterations in sediment characteristics resulting from microbe-mediated sulfide mineral precipitation were concomitant with changes in complex resistivity and acoustic wave propagation signatures. The sequestration of zinc and iron in insoluble sulfides led to alterations in the ability of the pore fluid to conduct electrical charge and of the saturated sediments to dissipate acoustic energy. These changes resulted directly from the nucleation, growth, and development of nanoparticulate precipitates along grain surfaces and within the pore space. Scanning and transmission electron microscopy (SEM and TEM) confirmed the sulfides to be associated with cell surfaces, with precipitates ranging from aggregates of individual 3-5 nm nanocrystals to larger assemblages of up to 10-20 microm in diameter. Anomalies in the geophysical data reflected the distribution of mineral precipitates and biomass over space and time, with temporal variations in the signals corresponding to changes in the aggregation state of the nanocrystalline sulfides. These results suggest the potential for using geophysical techniques to image certain subsurface biogeochemical processes, such as those accompanying the bioremediation of metal-contaminated aquifers.
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                Author and article information

                Journal
                Water Resour Res
                Water Resour Res
                10.1002/(ISSN)1944-7973
                WRCR
                Water Resources Research
                John Wiley and Sons Inc. (Hoboken )
                0043-1397
                1944-7973
                15 June 2015
                June 2015
                : 51
                : 6 ( doiID: 10.1002/wrcr.v51.6 )
                : 3837-3866
                Affiliations
                [ 1 ] Lancaster Environment CentreLancaster University Lancaster UK
                [ 2 ]Lawrence Berkeley National Laboratory Berkeley CaliforniaUSA
                [ 3 ] Agrosphere Institute (IBG 3)Forschungszentrum Jülich GmbH JülichGermany
                [ 4 ] Department of GeophysicsColorado School of Mines Golden ColoradoUSA
                [ 5 ] ISTerre, CNRS, UMR CNRS 5275Université de Savoie Le Bourget du LacFrance
                [ 6 ] Soils, Land and EcohydrologyCentre for Ecology and Hydrology Bangor UK
                [ 7 ] Department of Geology and Geological EngineeringColorado School of Mines Golden ColoradoUSA
                [ 8 ]Department of Earth and Environmental Sciences Rutgers‐Newark New JerseyUSA
                Author notes
                [*] [* ] Correspondence to: A. Binley, a.binley@ 123456lancaster.ac.uk
                Article
                WRCR21499
                10.1002/2015WR017016
                4744786
                26900183
                f98a2862-a0d0-4005-a808-2dfbd3e4f514
                © 2015. The Authors.

                This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

                History
                : 03 February 2015
                : 09 May 2015
                Page count
                Figures: 15, Tables: 1, Pages: 30, Words: 12646
                Funding
                Funded by: US Department of Energy under Award Number
                Award ID: DE‐AC02‐05CH11231
                Categories
                The 50th Anniversary of Water Resources Research
                Hydrology
                Hydrogeophysics
                Groundwater Hydrology
                Eco‐hydrology
                Biogeosciences
                Biogeophysics
                Review Article
                Review Article
                Custom metadata
                2.0
                wrcr21499
                June 2015
                Converter:WILEY_ML3GV2_TO_NLMPMC version:4.7.6 mode:remove_FC converted:03.02.2016

                hydrogeophysics,biogeophysics
                hydrogeophysics, biogeophysics

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