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      Nanocarbons for mesoscopic perovskite solar cells

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          Abstract

          This review outlines the progress that has been reported on using carbon based nanostructures in perovskite solar cells and discusses their possible further applications to deliver high efficiency, long lifetime, low cost PSCs.

          Abstract

          Organic–inorganic halides based perovskite solar cells (PSCs) have attracted a great deal of attention from the photovoltaic (PV) research community due to the extremely rapid increases in efficiencies observed over the past few years. The PSC is an extension of dye-sensitised solar cells and has reached an energy conversion efficiency of 19.3% by mid-2014. However, PSCs do have some disadvantages such as use of expensive metal electrodes, the high temperature required during production and poor stability when in use. There is no doubt that research with carbon nanomaterials will play an important role in understanding and solving the issues currently observed in PSCs, as they consistently have been shown to improve performance in a wide range of energy related applications. The present review (i) provides a brief introduction to PSC development; (ii) highlights the notable achievements of PSCs; (iii) particularly focuses on the use of nanocarbon in mesoscopic PSCs and (iv) predicts and suggests a roadmap for the future application of carbon materials in this emerging technology.

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          Most cited references71

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          Electric Field Effect in Atomically Thin Carbon Films

          We report a naturally-occurring two-dimensional material (graphene that can be viewed as a gigantic flat fullerene molecule, describe its electronic properties and demonstrate all-metallic field-effect transistor, which uniquely exhibits ballistic transport at submicron distances even at room temperature.
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            The rise of graphene

            Graphene is a rapidly rising star on the horizon of materials science and condensed matter physics. This strictly two-dimensional material exhibits exceptionally high crystal and electronic quality and, despite its short history, has already revealed a cornucopia of new physics and potential applications, which are briefly discussed here. Whereas one can be certain of the realness of applications only when commercial products appear, graphene no longer requires any further proof of its importance in terms of fundamental physics. Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed matter physics, where quantum relativistic phenomena, some of which are unobservable in high energy physics, can now be mimicked and tested in table-top experiments. More generally, graphene represents a conceptually new class of materials that are only one atom thick and, on this basis, offers new inroads into low-dimensional physics that has never ceased to surprise and continues to provide a fertile ground for applications.
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              Two-Dimensional Gas of Massless Dirac Fermions in Graphene

              Electronic properties of materials are commonly described by quasiparticles that behave as non-relativistic electrons with a finite mass and obey the Schroedinger equation. Here we report a condensed matter system where electron transport is essentially governed by the Dirac equation and charge carriers mimic relativistic particles with zero mass and an effective "speed of light" c* ~10^6m/s. Our studies of graphene - a single atomic layer of carbon - have revealed a variety of unusual phenomena characteristic of two-dimensional (2D) Dirac fermions. In particular, we have observed that a) the integer quantum Hall effect in graphene is anomalous in that it occurs at half-integer filling factors; b) graphene's conductivity never falls below a minimum value corresponding to the conductance quantum e^2/h, even when carrier concentrations tend to zero; c) the cyclotron mass m of massless carriers with energy E in graphene is described by equation E =mc*^2; and d) Shubnikov-de Haas oscillations in graphene exhibit a phase shift of pi due to Berry's phase.
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                Author and article information

                Journal
                JMCAET
                Journal of Materials Chemistry A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                2015
                2015
                : 3
                : 17
                : 9020-9031
                Article
                10.1039/C5TA00873E
                0c3d0105-4352-48d3-a36d-8adb8d6441aa
                © 2015
                History

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