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The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

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Angewandte Chemie International Edition

Wiley-Blackwell

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      Palladium-catalyzed ligand-directed C-H functionalization reactions.

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        Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.

        In the past decade, palladium-catalyzed C-H activation/C-C bond-forming reactions have emerged as promising new catalytic transformations; however, development in this field is still at an early stage compared to the state of the art in cross-coupling reactions using aryl and alkyl halides. This Review begins with a brief introduction of four extensively investigated modes of catalysis for forming C-C bonds from C-H bonds: Pd(II)/Pd(0), Pd(II)/Pd(IV), Pd(0)/Pd(II)/Pd(IV), and Pd(0)/Pd(II) catalysis. A more detailed discussion is then directed towards the recent development of palladium(II)-catalyzed coupling of C-H bonds with organometallic reagents through a Pd(II)/Pd(0) catalytic cycle. Despite the progress made to date, improving the versatility and practicality of this new reaction remains a tremendous challenge.
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          Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

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            Author and article information

            Journal
            Angewandte Chemie International Edition
            Angew. Chem. Int. Ed.
            Wiley-Blackwell
            14337851
            January 03 2014
            January 03 2014
            : 53
            : 1
            : 74-100
            10.1002/anie.201304268
            © 2014

            http://doi.wiley.com/10.1002/tdm_license_1.1

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