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      Metal–organic frameworks: a new promising class of materials for a high performance supercapacitor electrode

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          Abstract

          A layered structure Ni-based MOF was firstly used as the electrode material for a supercapacitor and exhibited a large specific capacitance of 1127 F g −1 at 0.5 A g −1.

          Abstract

          A layered structure Ni-based MOF was synthesized and, for the first time, was used as the electrode material for a supercapacitor. It exhibited large specific capacitance, high rate capability and cycling stability. Capacitances of 1127 and 668 F g −1 can be achieved at rates of 0.5 and 10 A g −1, respectively. At the same time, over 90% performance was retained after 3000 cycles. These excellent electrochemical properties may be related to the intrinsic characteristics of Ni-based MOF materials.

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          Most cited references38

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          Metal-organic framework materials as chemical sensors.

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            Hydrogen storage in microporous metal-organic frameworks.

            Metal-organic framework-5 (MOF-5) of composition Zn4O(BDC)3 (BDC = 1,4-benzenedicarboxylate) with a cubic three-dimensional extended porous structure adsorbed hydrogen up to 4.5 weight percent (17.2 hydrogen molecules per formula unit) at 78 kelvin and 1.0 weight percent at room temperature and pressure of 20 bar. Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which we associate with hydrogen binding to zinc and the BDC linker, respectively. Preliminary studies on topologically similar isoreticular metal-organic framework-6 and -8 (IRMOF-6 and -8) having cyclobutylbenzene and naphthalene linkers, respectively, gave approximately double and quadruple (2.0 weight percent) the uptake found for MOF-5 at room temperature and 10 bar.
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              Industrial applications of metal-organic frameworks.

              New materials are prerequisite for major breakthrough applications influencing our daily life, and therefore are pivotal for the chemical industry. Metal-organic frameworks (MOFs) constitute an emerging class of materials useful in gas storage, gas purification and separation applications as well as heterogeneous catalysis. They not only offer higher surface areas and the potential for enhanced activity than currently used materials like base metal oxides, but also provide shape/size selectivity which is important both for separations and catalysis. In this critical review an overview of the potential applications of MOFs in the chemical industry is presented. Furthermore, the synthesis and characterization of the materials are briefly discussed from the industrial perspective (88 references).
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                Author and article information

                Journal
                JMCAET
                J. Mater. Chem. A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                2014
                2014
                : 2
                : 39
                : 16640-16644
                Article
                10.1039/C4TA04140B
                a3957f99-2912-41a5-b524-9bd2377d612c
                © 2014
                History

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